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Product Details

Manufacturer
Thermo Scientific
SKU
10238463

About this product

Tetrabutylammonium Hydrogen Sulfate, 99%

Tetrabutylammonium hydrogen sulfate (TBAHS) is a quaternary ammonium salt with the formula [(C₄H₉)₄N]HSO₄. It is a white to off-white crystalline solid or powder used widely as a phase-transfer catalyst (PTC) in organic synthesis, particularly in biphasic reactions involving aqueous and organic phases.

Specifications:

  • Chemical Formula: (C₄H₉)₄NHSO₄

  • Molecular Weight: 339.56 g/mol

  • Appearance: White to off-white powder or crystalline solid

  • Purity: ≥ 99%

  • Solubility:

    • Soluble in water, methanol, ethanol, and some organic solvents

  • Melting Point: ~125–130 °C (may vary slightly by batch)

  • Storage Conditions:

    • Store in a cool, dry place, tightly sealed, away from moisture and strong oxidizers

  • CAS Number: 32503-27-8


🧪 Uses:

  • Phase-Transfer Catalysis (PTC):

    • Facilitates reactions between aqueous and organic immiscible phases, enhancing reaction rates and yields

  • Organic Synthesis:

    • Useful in alkylation, oxidation, epoxidation, nucleophilic substitution, and esterification reactions

  • Ion-Pairing Agent:

    • Used in chromatography and electrochemistry for ion pairing and improving separation

  • Catalyst Support:

    • Often used in micellar catalysis and ionic liquid systems

  • Surfactant and Solubilizer:

    • Enhances solubility of reagents in water-organic biphasic systems


🔍 Features (Bullet Points):

  • High Purity (99%) for reliable and reproducible performance in sensitive reactions

  • Effective Phase-Transfer Catalyst for aqueous-organic reaction systems

  • Stable and Non-Volatile: Easily handled in lab conditions

  • Broad Solubility Profile: Compatible with both polar and nonpolar solvents

  • Enhances Reaction Kinetics and facilitates reactions with low aqueous solubility substrates

  • Mild Handling Requirements: Not highly hazardous under normal lab use

  • Reusable Catalyst in some reaction cycles under mild conditions

 

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